Season & Sear the Pork Chops:
Pat pork chops dry and season both sides with salt and pepper.
Heat olive oil and butter in a large skillet over medium-high heat.
Sear the pork chops for 3–4 minutes per side, until golden brown and cooked through (internal temp: 145°F/63°C). Remove from skillet and set aside.
Make the Pineapple Sauce:
In the same skillet, add garlic and sauté for 30 seconds.
Stir in pineapple juice, brown sugar, soy sauce, and vinegar.
Let the sauce simmer for 3–4 minutes, allowing it to reduce slightly.
If you’d like a thicker glaze, mix cornstarch with water and stir it in, simmering until thickened.
Add Pineapple & Return Chops:
Add pineapple slices to the skillet and cook for 1–2 minutes until lightly caramelized.
Return pork chops to the skillet and spoon sauce over them. Simmer together for 2 minutes to soak up flavor.
Serve:
Plate pork chops with pineapple slices on top and drizzle with extra glaze.
Garnish with green onions, sesame seeds, or a pinch of red pepper flakes if desired.