Preheat the air fryer to 400°F for 5 minutes.
Stir panko, Parmesan, 1 tbsp olive oil, paprika, garlic powder, onion powder, salt, pepper, and cayenne in a shallow bowl.
Pat pork chops dry. Rub a thin layer of mayonnaise over both sides.
Press each chop into the crumb mix, coating well and shaking off any excess.
Brush the air fryer basket with the remaining 1 tsp olive oil. Arrange chops in a single layer.
Air fry 10–12 minutes, flipping halfway, until the center reaches 145°F.
Rest chops 5 minutes so juices settle, then serve hot.